For the layers obtained by spin coating of a solution of cluster 5 , it was found that the cluster is not attached to the surface, but only deposited on it. You may thus request that your data, should it be inaccurate, incomplete, unclear, outdated, not be used or stored, be corrected, clarified, updated or deleted. Amazon Second Chance Pass it on, trade it in, give it a second life. Learn more about Amazon Giveaway. Enter your mobile number or email address below and we’ll send you a link to download the free Kindle App. Personal information regarding our website’s visitors, including their identity, is confidential. Not Enabled Screen Reader:
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Two approaches have been used to anchor the heterometallic palladoum on the surface and generate monolayers. The first process consisted of depositing cluster 5 by spin coating on a gold surface.
The second was the immersion of a gold surface into pallzdium cluster solution. For both procedures, the resulting deposits were analysed by STM scanning tunneling microscopyellipsometry and XPS X-ray photoelectron spectroscopy.
For the layers obtained by spin coating of a solution of cluster 5it was found that the cluster is not attached to the surface, but only deposited on it. In contrast, after immersion of a gold substrate into a solution of 5 or 6anchoring of the complexes was clearly evidenced by XPS via the chemical shift of the S—2p binding energy toward lower binding energies. Ces couches ont ensuite été analysées par STM Scanning tunneling microscopypar ellipsométrie et par spectroscopie XPS X-ray photoelectron spectroscopy.

Mixed-metal clusters, Self-assembly, Gold surfaces, Spectroscopy, Scanning tunneling microscopy, X-ray photoelectron spectroscopy. Journal page Archives Contents list.
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Access to the full text xrzy this article requires a subscription. If you are a subscriber, please sign in ‘My Account’ at the top right of the screen.
If you want to subscribe to this journal, see our rates You can purchase this item in Pay Per Plaladium Synthesis of functional heterometallic complexes and clusters containing molybdenum and palladium or platinum, their self-assembly on gold surfaces and X-ray photoelectron spectroscopic studies.
Outline Masquer le plan. Preparation of the samples and analyses of the resulting layers. Top of the page – Article Outline. Contact Help Who are we? As per the Paladium relating to information storage and personal integrity, you have the right to oppose art 26 of that lawaccess art 34 of that law and rectify art 36 of that law your personal data.

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Results and discussion Synthesis and characterization of the heterometallic complexes. Experimental part Preparation of the gold substrates.
Electronic supplementary information ESI available: CCDC reference numbers
